General assignment 1

                                                                ACID RAIN

INTRODUCTION

Acid rain is rain consisting of water droplets that are unusually acidic because of atmospheric pollution - most notably the excessive amounts of sulfur and nitrogen released by cars and industrial processes. Acid rain is also called acid deposition because this term includes other forms of acidic precipitation such as snow.  Acidic deposition occurs in two ways: wet and dry. Wet deposition is any form of precipitation that removes acids from the atmosphere and deposits them on the Earth’s surface. Dry deposition polluting particles and gases stick to the ground via dust and smoke in the absence of precipitation. This form of deposition is dangerous however because precipitation can eventually wash pollutants into streams, lakes, and rivers. Normal rain water is slightly acidic and has a pH range of 5.3-6.0. Acid deposition is anything below that scale. It is also important to note that the pH scale is logarithmic and each whole number on the scale represents a 10-fold change. Today, acid deposition is present in the northeastern United States, southeastern Canada, and much of Europe including portions of Sweden, Norway, and Germany. In addition, parts of South Asia, South Africa, Sri Lanka, and Southern India are all in danger of being impacted by acid deposition in the future.

CAUSES OF ACID RAIN

Acid rain describes any form of precipitation with high levels of nitric and sulfuric acids. It can also occur in the form of snow, fog, and tiny bits of dry material that settle to Earth.

Rotting vegetation and erupting volcanoes release some chemicals that can cause acid rain, but most acid rain falls because of human activities. The biggest culprit is the burning of fossil fuels by coal-burning power plants, factories, and automobiles.

When humans burn fossil fuels, sulphur dioxide (SO2) and nitrogen oxides (NOx) are released into the atmosphere. These chemical gases react with water, oxygen, and other substances to form mild solutions of sulphuric and nitric acid. Winds may spread these acidic solutions across the atmosphere and over hundreds of miles. When acid rain reaches Earth, it flows across the surface in runoff water, enters water systems, and sinks into the soil.

EFFECTS OF ACID RAIN

After studying the Hubbard Brook Forest and other areas today, there are several important impacts of acid deposition on both natural and man-made environments. Aquatic settings are the most clearly impacted by acid deposition though because acidic precipitation falls directly into them. Both dry and wet deposition also runs off of forests, fields, and roads and flows into lakes, rivers, and streams.

As this acidic liquid flows into larger bodies of water, it is diluted but over time, acids can accrue and lower the overall pH of the body. Acid deposition also causes clay soils to release aluminum and magnesium further lowering the pH in some areas. If the pH of a lake drops below 4.8, its plants and animals risk death and it is estimated that around 50,000 lakes in the United States and Canada have a pH below normal (about 5.3 for water). Several hundred of these have a pH too low to support any aquatic life.

Aside from aquatic bodies, acid deposition can significantly impact forests. As acid rain falls on trees, it can make them lose their leaves, damage their bark, and stunt their growth. By damaging these parts of the tree, it makes them vulnerable to disease, extreme weather, and insects.  Acid falling on a forest’s soil is also harmful because it disrupts soil nutrients, kills microorganisms in the soil, and can sometimes cause a calcium deficiency. Trees at high altitudes are also susceptible to problems induced by acidic cloud cover as the moisture the clouds blankets them.

Damage to forests by acid rain is seen all over the world, but the most advanced cases are in Eastern Europe. It’s estimated that in Germany and Poland, half of the forests are damaged, while 30% in Switzerland have been affected.

Finally, acid deposition also has an impact on architecture and art because of its ability to corrode certain materials. As acid lands on buildings (especially those constructed with limestone) it reacts with minerals in the stones sometimes causing it to disintegrate and wash away. Acid deposition can also corrode modern buildings, cars, railroad tracks, airplanes, steel bridges, and pipes above and below ground.

Stone Buildings and Monuments in Acid Rain

Marble and limestone have long been preferred materials for constructing durable buildings and monuments. The Saint Louis Art Museum, the Parthenon in Greece, the Chicago Field Museum, and the United States Capitol building are all made of these materials. Marble and limestone both consist of calcium carbonate (Ca CO₃), and differ only in their crystalline structure. Limestone consists of smaller crystals and is more porous than marble; it is used more extensively in buildings. Marble, with its larger crystals and smaller pores, can attain a high polish and is thus preferred for monuments and statues. 

How does this happen? A chemical reaction between calcium carbonate and sulfuric acid (the primary acid component of acid rain) results in the dissolution of CaCO₃ to give aqueous ions, which in turn are washed away in the water flow.

This process occurs at the surface of the buildings or monuments; thus acid rain can easily destroy the details on relief work (e.g., the faces on a statue), but generally does not affect the structural integrity of the building. The degree of damage is determined not only by the acidity of the rain water, but also by the amount of water flow that a region of the surface receives.